Hi liuqimin,
The problem that you encountered is caused by the IAR8.0 folder, which differs a little bit from the version 7.5, the latest IAR version when Kinetis Toolbox was released.
Indeed your compiling issue is related with that COPY CATCH exception from the log.
The Toolbox tries to use the file located in the C:\Program Files (x86)\IAR Systems\Embedded Workbench 8.0\arm\src\lib\write.c but now, in the IAR8.0, the write.c is located here C:\Program Files (x86)\IAR Systems\Embedded Workbench 8.0\arm\src\lib\file\write.c.
This can be solved either by copying the write.c file in the old location (one folder above) or by replacing in the {Kinetis Toolbox install path}src\mctbx_kv5xf\mctbx_kv5xf\mscripts the mcd_kv5xf_copy_required_files.p file attached to this response, obviously after you made a copy of the existing file.
Please tell us what you tried and if worked.
I hope this helps,
Marius