Yes, it is possible to use the SW3A and SW3B regulators of the MMPF0100 PMIC separately and independently, as shown on your schematic. Please note that a custom OTP configuration should be used for that.
Also, please note that it is recommended for the MMPF0100 PMIC (refer to the AN4717 document) to connect the inputs of even unused switching regulators (SW4IN and SWBSTIN in your case) to VIN, whereas these inputs are left floating on your schematic. Please fix this as well.
Have a great day,
Artur
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