Hi Harshit,
First off, I apologize for my late response, I was on vacation last two weeks.
1.

FXOS8700CQ - 6-axis accelerometer/magnetometer sensor
FXAS21002 - 3-axis gyroscope
FRDM-STBC-AGM01 - Development board with FXOS8700C and FXAS21002C
2. Initial calibration is required and is done automatically by the fusion software.
3. The sensor fusion software has been written primarily for hand-held devices, but with some modification it should work in vehicle-based devices as well.
4. I am not aware of any rollover detection algorithms provided by NXP.
5. There is a portability discussion at Portability Topics · memsindustrygroup/Open-Source-Sensor-Fusion Wiki · GitHub
Best regards,
Tomas