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BCTU is most flexible way trigger ADC instances.
Please refer to the provided example in the following community post for a BCTU -> ADC -> DMA configuration for parallel conversion:
https://community.nxp.com/t5/S32K/Questions-about-3xADC-and-BCTU-S32K344/td-p/2128105

It is possible to separately acquire the data from ADC0 and ADC1.
You can use a BctuInternalTrigger_0 for ADC0 configuring Adc Target Mask = 0b001.
And a second BctuInternalTrigger_1 for ADC1 configuring Adc Target Mask = 0b010.
You should configure the Bctu LIST Items for all ADC instances, but you can separate them using Conversion List Start Index and Last Channel boxes.
Additional examples can be found in the following post:
https://community.nxp.com/t5/S32K-Knowledge-Base/RTD400-LLD-K344-ADC-SW-HW-trigger/ta-p/1966179
I hope this information is helpful.