Hello Joe,
The Knox MCU on Picture is ZVL32 and VRH & VRL connection is described in RM Sec.1.9.1.2. This is ADC12B_LBA version V1.
The ZVL128 has ADC V2.
The detail information about those reference pins is in Figure 10-2 and Sec. 10.4.1.2. Sorry that there is no Table with clear information about ADC versions in RM.
The extra reference pins (VRH or VRL) can be used for the special analog measurements where the reference points are not equal to VDDA and VSSA. Then the ADC result in data register reflects the range from VRL to VRH (e.g. from 1.0V to 4.0V). In this case the VRL and VRH levels can be measured by ADC inputs together with analog value in this range and then the accurate analog value is calculated.
The information about allowed VRH and VRL range is in Table C-1 in RM.
I hope this helps you to solve your task.
Best Regards,
Stano.