Hello @Sriram,
In your thread, you are referring to Appendix D of the AN12217, but your configuration example inside the MBDT does not quite match any of the Appendices of the AN12217. Let me explain.
1. Appendix D configures an external pin to be muxed to the TRGMUX_IN0 trigger source. This one is connected using the TRGMUX to the ADC0_SCA via the ADC Trigger Latching and Arbitration Unit. The 4 channel limitation you mention here is valid but only for this scenario. In other words, when an event appears on the TRGMUX_IN0, such signal automatically triggers an ADC channel, so that the conversion occurs and no PDB is involved. This scenario cannot be achieved in MBDT directly via our blocks and involves custom code usage.
2. In your configuration, things are working differently. Here, the TRGMUX signal is routed to the PDB, and the PDB triggers the ADC. This is why you are able to convert 5 ADC channels.
So the FTM0 initialization trigger (TRGMUX_in22) is connected via TRGMUX to the TRGMUX_PDB_TRIGGER (PDB0_trigger_in0).

When such input occurs, the PDB starts counting, and when each of the channels' values matches the PDB internal counter, PDB directly triggers the ADC channels, because the ADC is set to have the PDB as Trigger source, not TRGMUX.

This MBDT configuration is based on the Appendix B of the AD12217 but instead of using the Software Trigger of PDB, this uses the FTM0 via TRGMUX to trigger the PDB.
So in this case/configuration exemplified in MBDT, you can trigger up to 8 ADC channels/per PDB instance. if you need more than 8 channels, then you can use the both PDB instances, like described below.

Hope this helps,
Marius