Hello Lijo Francis:
You can change configurations between transfers by using the SPIx_CTARn registers. Then from the SPIx_PUSHR register as stated by Mark you would select the slave to communicate with as well as the CTAR to use with the field SPIx_PUSHR[CTAS]. Refer to SPI chapter in Reference Manual for more details about CTAR registers. If you have further doubts please let us know.
Regards!,
Jorge Gonzalez
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