Adam
I checked and agree that if you attach the PDB pulse output to the CMP and set its other input to, say 1.6V (from 6-bit DAC) it should generate a pulse on the CMP out pin (when configured for this peripheral mode). Therefore it is worth trying - please tell us if it works as expected.
Note that I tend to use the DMA method since it allows such things to be done on any output (or multiple outputs), which is especially useful when the HW design has already been completed and it is realised that such a function could be useful (without need to change the board design).
Regards
Mark