Hi @aberger
I really appreciate that you were so patient. Our backlog increased a lot due positive covid tests at the office. Please accept my apologies for late response.
After double checking your issue on what you are trying to understand, I think you are wrong when you say "The ADC specification suggests about 6 LSBs of full-scale error (or 0.02% error).", because checking the Reference Manual you can see the following:
PabloAvalos_0-1658451548555.png
Based on this, you will need to consider that the difference between your conversion code width when you have maximum voltage (measured 3.296V) and the ideal code width (1 LSB = 3.3V) is the one that is going to be used, and that's why you see 32133 as your maximum code.
Hope this is helpful, please let me know your comments or if you have more questions.
Best Regards.
Pablo Avalos.