Hi Eric,
No, the ADC and ACMP cannot be used simultaneously. You can switch from ACMP to ADC and back. You need to set the pin as ACMP make the measurement, turn off the ACMP module and the set the ADC, make the measurement and then turn off the ADC module.
Since Processor Expert will not let you use both components with the same pin you need to first configure one of the components, generate the code and copy the source files to another folder inside your project, after that disable the component and configure the second one.
Hope it helps!
Best Regards,
Carlos Mendoza
Technical Support Engineer