Hello Tomaru,
Could you help us confirm what configuration are your using? As I see DCDC Buck mode in the image. [Bypass mode, DC-DC Buck mode,PMIC mode, DC-DC mode controlled with Smart Power Switch]
In the block diagram, Yellow Block represents MCU, the connections inside this block are internally, the connections outside are from external circuit, in the Hardware Design recommendation there is an image of the MCU, and the external components connected to this as reference. [Review your desired configuration in DCDC modes Chapter]
KW45-K32W HARDWARE DESIGN RECOMMENDATION guide
VDD_LDO_CORE has an internal connection with LDO-CORE but need an external supply configuration as the image on Design recommendations shows the value from the Source and capacitors values.
VDD_PA_2G4[VPA_2P4GHZ]is internally connected to the VDD_RF pin. VDD_RF pin gets the external source supply and with the internal connection supply VPA pin,
For more information, please refer to Table 41 2nd Note description in KW45 Datasheet and the images for DCDC configuration in HW Design Recommendations.
For the LDO_SYS configuration I would recommend referring to Table 16 LDO_SYS specifications in KW45 Datasheet.
Also, the recommended connection for unused interfaces can help you with the LDO configuration if needed. Table 62 in Datasheet.
Best Regards
Luis