Hi David,
You are correct, first case is possible based on the specs, but it would be unlikely to occur. We do not have any data indicating how likely the first condition is to occur, or any data that indicates typical expected linearity of these sensors other than the mentioned in the datasheet, however, in order to occur this condition, the error factors need to be very variant, these factors includes: Pressure Error (not likely to change during time), Temperature Factor (would be a problem if varying below 0C or above 85C), and Voltage supply (output of the sensor is ratiometric with the input voltage, so changes in the input, would cause changes in the output).
Regards,
Jose