Hi @aadhi_402,
FlexCAN itself is also not in Standby Power Domain, so you can't use the FlexCAN module directly to wake up the chip. But you can use the WKPU unit and the external pins. Refer to this post: Solved: S32K3 Wake up method - NXP Community. So yes, you can multiplex the pins to wake up the MCU, but it is not possible to simulate the MCU behavior, this needs to be tested with HW.
You can use these following examples as reference (S32DS 3.4 RTD 2.0.0): S32K3 Low Power Management AN and demos - NXP Community. There is a specific case for FlexCAN wake up.
The first CAN frame can't be fully received since there will be some time for the MCU to warm up from standby mode to run mode, so the application needs to ignore this CAN frame.
For the GPIO of S32K3, it can be set to multiple input functions simultaneously while it can be set to 1 output function (writing MSCR) at once. You can refer to the IO table attached to the S32K3's reference manual.
Also, as a note, if your inquiry is urgent, next time you enter a ticket please ensure that you use your company email address when communicating with NXP so that we can prioritize your question accordingly. Thank you for your understanding.
Best regards,
Julián