Hello,
I hope all is great with you. Thank you for using the NXP communities.
You are correct. The SYNC signal scheduling enables MC33665A to synchronize the activities such as voltage, temperature and current measurements across the battery pack working with BCC devices on TPL2 and TPL3 protocol.
I would recommend the procedure below considering that the request queue is empty:
- Send a TPL message to MC33665A
- Send a TPL2 or TPL3 message that needs to be scheduled for sync signal.
- Send a trigger signal (TRIG) for SYNC (GPIO6).
- Send a TPL message to MC33665A.
For further information, I do recommend downloading the document below from your Secure Files. Note that such document is confidential and provided only with an active NDA number.

I hope this information helps.
Regards,
David