Hi @ScottXing,
S32K144 does support CANFD:
Julin_AragnM_1-1709762879773.png
do you have FRZACK set as well to indicate module is truly in Freeze mode? Even if both FRZACK and FRZ are set 1, but FDEN still cannot be set to 1, you can try to change FDEN within debugger directly, while in Freeze mode.
Best regards,
Julián