Hi,
Thanks for your feedback. We don't fully understand the following statement:
"In our application measurements are required in active mode only, but the input to ADC pins continuously available in standby mode and active mode"
You are saying that the ADC will only be used on active mode but it will be connected to always on power rails?
If so, as said under the checklist, this is not allowed. If measurements of the always on power rails are not required under standby mode, then you should be able to disconnect the rails with a switch, which will be turned on only in active mode.
As for the TMU, this is the recommended connection for TMU test inputs, as shown under the checklist:

If more information is required on regards of the TMU, we can recommend looking into the Chapter 59 of the S32G2 Reference Manual [S32G2 Reference Manual, Rev. 7, February 2023].
Please, let us know.