You can start conversion sequence from channel other than AN0. With default WRAP setting or on older S12 which don't have WRAP bits, you could start for example sequence of 8 channels from AN12. That would convert channels AN12 to AN15, then AN0 to AN3. I didn't try any wrapping myself yet, but I think with wrap set to 13, you could convert AN12,AN13, then AN0 to AN5. This makes sense in case tight layout asks you to skip some ATD pins.