Hello
It is not normally possible for the S12XEP100 to generate 4.2V at the VDDPLL pin.
The presence of 4.2V at the VDDPLL pin indicates either device internal damage or a PCB shortcircuit.
Can you isolate the VDDPLL pin from the rest of the board (for example by bending the pin) and measure VDDPLL on the pin on then on the board, to determine the source?
What voltage is applied to VDDR, VDDX and VDDA?
Could the low VDD and VDDF voltages be caused by an incorrect polarity of a tantalum capacitor causing damage to it?
In the schematic attachment the VSSA1 connection seems to be floating but I guess this was just shifted when drawing the power routing diagram.
DPB