Hi Norman,
In sections 11.3.2 and 11.3.3 of the Data Sheet are some illustrations of the FD behavior when the pass-through mode is enabled. In case of NFC->I2C communication, the NC_REG value is 7Dh (PTHRU_ON_OFF = 1, FD_OFF = 1, FD_ON = 1, TRANSFER_DIR = 1).
In case of I2C->NFC the NC_REG value is 7Ch (PTHRU_ON_OFF = 1, FD_OFF = 1, FD_ON = 1, TRANSFER_DIR = 0).
I cannot help you from your MCU side, but this is the configuration needed for the FD pin.
Regards,
Ricardo