Hi @Automan
Thank you for using our latest NXP Model-Based Design Toolbox for S32K3 version 1.6.0.
We also have a guide on how to enable a new ADC channel for S32K3 boards Controlling LED intensity with ADC and PWM - NXP Community
In your case with the the S32K31XEVB-Q100 EVB board, there is only one ADC1 channel configured in the S32CT.
If you want to add an ADC0 channel, we need to first add a pin intro Pin Manager:

For example PTE11 pin is on ADC0 and connected to TOUCHO_A on the board.
Next we need to add thisPTE11 pin in Peripherals -> Port Configuration:

Then we need to enable the ADC0 interrupt in Platform Configuration -> Interrupt Controller:

Scroll down the Interrupt Controller page and find and enable ADC0:

Then we need to enable the ADC0 peripheral clock in MCU Configuration -> McuModuleConfiguration -> McuModeSettingConfig:

We need to add ADC0_EOC and ADC0_WD in ADC Configuration-> ADC Interrupt:

Then we need to add another ADC Hardware Instance in ADC configuration:

After we need to configure the Channel configurations array P6_ChanNum6:

Update the Adc0Group_2 with the Adc_Adc0Group2Notification in the Group configuration array:

Select the AdcChannel_1 in the AdcGroupDefinition:

After this we can Update Code and a pop-up Update Files will appear, press OK:

After this process is done, we can close S32CT and go back to the model.
Update in the s32k3xx_adc_single_read_s32ct model, with Adc0Group_2:


Then go back to MATLAB and delete the following:
- s32k3xx_adc_single_read_s32ct_ert_rtw
- slprj
- s32k3xx_adc_single_read_s32ct.slxc

Select Yes to all, then go back to the s32k3xx_adc_single_read_s32ct.mdl and press on Build, Deploy &Start (keyboard shortcut CTRL+B

After the generated code is automatically flashed into the S32K311EVB, open FreeMaster and watch the newly added Channel_1:

Hope the steps above help you,
Stefan V.