The MPC5200B Chip Select pins and PSC6 pins are independent pins.
See the Table 2-24 of the MPC5200B Reference Manual.
Perhaps there is unexpected short-circuit between the Chip Select 1 and PSC6_3.
Check your board about unexpected short-circuit between the Chip Select 1 and PSC6_3.
Have a great day,
Pavel Chubakov
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