Hi Berat,
the BOOTCFG pins are latched at the end of the reset cycle. So, you should externally force the pins to required state, reset the MCU and the MCU will start in serial boot mode after reset release.
Notice that BOOTCFG pins have effect only in legacy mode (can be changed by Miscellaneous DCF record, legacy mode is default) and when life cycle is different than "In Field".
lukaszadrapa_1-1643730095746.png
And regarding the second question:
lukaszadrapa_0-1643730021690.png
Regards,
Lukas