Please, take a look at the BLE Application Developer's Guide Bluetooth Low Energy Application Developer’s Guide . Chapter 5 Generic Attribute Profile (GATT) Layer, Section 5.1 Client APIs provide some procedures and APIs to configure ATT MTU, discover Services and Characteristics, and initiate data exchanges. Also, Section 5.1.2 MTU exchange describes the ATT packet, its default size, exchange procedure.
While is it recommended to design small attribute value sizes, GATT layers as Wireless UART can only send 23 bytes of data in a radio packet setting the ATT packet default length to 23, The ATT packet length is set to maintain a logical mapping between radio packets and ATT packets.
I would strongly recommend checking the series[1-4] of community post Bluetooth Low Energy - Working with long attributes on a GATT Server - Part 1: ATT_MTU - NXP Communi... if you need to send more bytes of data, as explains how to write long attributes involves writing queues, and modifying the ATT_MTU for both GATT client and server to support larger MTU with MTU exchange.
Could you help us confirm if you can test the wireless uart example without increasing the packet size, just modifying the number for multiple connections with the instruction in Chapter 9.10 for both client and server please?