I guess you use LPC824 HVQFN33 package package.
this chip totally has 32pins. Vdd, Vrefp, Vrefn can't be used as GPIO.
Other 29 pins: in debug phase, SWDCLK and SWDIO are used as debug interface. if you need reset feature, PIO0_5/RESET is used as reset. others can all work for GPIO.
Have a great day,
Jun Zhang
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