Hi Johan,
1. If the USART is transmitting in synchronous mode, does the signal transition on the rising or falling edge of SCLK,
You can find the according information in the datasheet.

You can find, when UART is transmitting, it still determined by the CLKPOL.
1. CLKPOL=0, rising is changing data, falling is acquiring data.
2. CLKPOL=1, falling is changing data, rising is acquiring data.
The USART timing is very clear.
Wish it helps you!
If you still have question, please let me know!
Have a great day,
Kerry
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