> We Verify that LED Toggle's in the Debug mode, But after the Releasing the Debugger it is not Blinking.
Are you sure you are not fooled ? A blinking beyond 70...80Hz looks like a static state, better check it with a scope.
Many initialisation fails manifest in the startup code, before main is reached.
A simple instrumentation code could e.g. write successive byte values to a serial interface (UART), just attach a serial terminal.
An even simpler method would be to toggle a GPIO before or after each step, but you would need a scope to check that. I used this method in one of my former companies, for a project without debug access to the MCU.