Yes, the LPC5514JBD64 can be used to drive WS2812 LEDs, although it may require configuring a timer/SCT or SPI-based interface to generate the precise WS2812 timing. For a beginner, I recommend starting with NXP’s MCUXpresso SDK examples and WS2812 driver examples, then adapting them to the LPC5514; the LPC5514 SDK documentation and sample code are available through NXP’s official MCUXpresso resources.