Hello,
Do I have to do is measure the "ta us"? I found it is <= 20us. And My conditon is when MCU power down to 2.5V and then ramp up, it also can not start up.
Not really, we need to analyze where the power-on starts until the behavior you describe.
I measured the time from 2.5V to 3.3V,it is 160us.
Could you share the image of your measure? please.
By the way ,my operation is turn off the power switch and the turn on.If the power fell below 1V,MCU can start up.
Well, if the power falls below 1V is under spec, and need to follow the start-up again.

Best regards,
Pavel