Hi,
Unfortunately there is no such document which list the pin assignments as Processor Expert does, but is easy to understand with some help from the Reference Manual.
All the pins are by default in its analog configuration, this for high impedance. All of them can be configured as different signals, e.g:

Thus this Pin can be configured as an ADC channel or a Touch Sensing channel or GPIO or External Trigger or Comparator Output. All the pins have their GPIO function in ALT1 it means that in PEx format will be the second or the third; and the first will be its analog configuration, in this case it is ADC channel 14.
Regards.