Hi Sean Law,
it is mentioned in the datasheet specification, that the difference between VREFH and VDDA can be max 100mV (Table 30). Each pins is protected by pair of clamping diodes. If the difference VREFH - VDDA > 100mV the current starts to flow through the clamping diode to VDDA line. The diodes are usually designed for currents from 2 to 10mA max. The repercussion of this could be VDDA out of range or damaged clamping diode.
The measurement range is defined by VREFL to VREFH. Usually VREFL = VSS. Then VREFH is divided by 12/16 bit. The measured value has to be in this range, otherwise the values higher than VREFH will be measured as max (0x0FFF or 0xFFFF).
The use of two separated power supplies for VDDA and VREFH is dangerous. It is not maintained right voltage level on those pins during switch ON and OFF process. So the best way is to use one DC power source for VREFH and VDDA. VREFH has to be connected by low pass filter - small inductance with dedicated blocking capacitor to avoid noise on VREFH pin.
I think this could help you.
Best Regards,
Stano.