Hi
ADCs are 16 bit resolution but the maximum achievable accuracy (with longer conversion time and HW averaging) is about 14.5 bits (although can be worse depending on signal noise and power supply coupling, cross-talk, etc.).
16 bit accuracy is never possible with the ADC in the Kinetis parts (check the data sheet for maximum possible accuracy). Eg:

Regards
Mark
uTasker developer and supporter (+5'000 hours experience on +60 Kinetis derivatives in +80 product developments)
Kinetis: http://www.utasker.com/kinetis.html