Hello Carsten,
From the Reference manual of K02, the ADC input signal of "ADC0_SE4a" and "ADC0_SE4a" use the same pin PTE16,
and in the PE ,we can see the "A/D channel(pin)" selection is pin , so i think this button only can identify which pin ,while this
pin has TWO ADC channel , so it show error . When we select the channel as "ADC0_SE4b" or others , it will no error.
And if you want use "ADC0_SE4a" , i recommend you configure it us code , please refer to the demo code under SDK installation directory:
KSDK_1.2.0\examples\frdmk22f\driver_examples\adc16 :
in the demo code , you can see the configuration of the channel as this :



For example , if you want use che ADC0_SE4a , you can change it to :
| #define ADC16_TEMPERATURE_CHN | (kAdc16Chn4 ) |
And please pay attention to this : in the PE configure window , when the selection show this symbol of red , it meaning it can not select :

Hope it helps
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Have a great day,
Alice