Hi,
1. Yes. As long as the processor start-up sequence is followed, the voltage levels are met and the POR_B signal is released after the power up sequence has finished, the processor will turn on.
2. PMIC_ON_REQ is a processor signal that turrns on the PMIC, but it actually doesn't affect the processor turn-on. The signal you should be looking at is POR_B. As I mentined, it must be asserted right after the power-up sequence finishes. You will need to control it with a voltage level equal to VDD_SNVS_IN, since this is the reference voltage of POR_B.
3. Yes, PMIC_ON_REQ is asserted with an ONOFF button press.
4. Not sure I understand this question. If the info above is not enough and you still need an answer on this, could you please elaborate?
5. PMIC_ON_REQ signal will stay high as long as the processor is on, and will go low when the system requires to turn off or go to sleep.
Best regards.
Jorge.