1. i2c has no spec. It is user manual now. Of couse, some version says spec. But not now vesion.
2. the falling time tf in the UM10204 is Start(S)/repeated Start(Sr). It just gives time for sampling the start condition and make sure it is a start condition. For others, it should be as fast as possible to fall to get ready for next bit. For others(not detecting start condition), no meaning. Because the data sampling is on the raising edge. And if you read the UM10204, the tf is only tagged on S of the wavefrom.
3. make sure, you measure the S/Sr.
4. a little difference between S and Sr. In the UM10204, no tf of Sr, it says/measures in different way, accually.