Hello Steffen,
Tell me if the following scenario is suitable for you.
Flash a board with ble_thread_router_wireless_uart which you will find in hybrid examples in SDK. Flash another board with an end_device. Now go into IoT Toolbox app, go for Thread Shell app and scan for the hybrid device. After you see it and connect to it, you will be notified by Android to pair with the device, the passcode is 999999.
Now you have a Thread shell you can control via your phone/tablet. For example, you can create a Thread network from your phone/tablet and to see that it worked you can connect the end device to it. Now that the two Thread devices are connected, you can send a CoAP message to toggle the LED (help coap in shell to see more details on how to do this).
Please tell me if you need more assistance with this.
Regards,
Lilian