Dear @edelh ,
In general, the device usually boots from external flash memory, including eMMC, QSPI Flash, etc. Booting from Serial Boot mode is a configuration step before flashing the binary. By setting the S32G - RDB3 to this mode, you can use tools such as S32 Flash Tool to write the binary image to the external flash memory.
After the flashing is completed, the device will boot from the corresponding external flash memory (such as eMMC, QSPI Flash, etc.) according to the configuration, rather than from the Serial Boot mode. The Serial Boot mode is just a configuration mode during the flashing process, which supports writing the binary through the serial port. For more details, please refer to the document AN13456.
Regarding Serial Boot, you can refer to the document "AN14136 Enabling Serial Boot in S32G".
The mentioned documents are available under the "Search" of the NXP official website (link: Search | NXP Semiconductors), as shown below.

Best Regards,
Celeste