Zircon,
Thanks for the further info.
I read the datasheet for the SLIC part, and was impressed by how little they said about the "PCM Highway".
I then searched the web, and found a 10 page application not from AMD:
titled "Mysteries of the PCM Highway"
Which tells a great deal about the "PCM Highway".
The "PCM Highway" is certainly not standard SPI or SCI.
It is clearly designed as a way of multiplexing many SLIC parts as part of a switching system. The AMD applications seems to make sense with the SLIC datasheet.
It might be possible to fool the SPI interface into reading and writing one or more SLIC parts, but it won't be simple. Since the clock comes from the SLIC electronics, the SPI interface on the MCU would have to be configured as a slave. (I don't remember which devices and mask sets are involved, but some HCS-12 parts have confusing errata associated with SPI slave configuration.)
It would probably be simpler if you had some external hardware to translate from the PCM clock and FSYNC signal to SPI control signals.
I don't understand how much freedom you have in configuring this system, but I'd suggest at least the extra hardware, and probably an MCU with 2 SPI interfaces, which won't cost much more.
I'd also see if there are less complicated SLIC chips available with friendlyier MCU interfaces.
Please tell us more about what your project requirements are.