Hello Massimiliano:
Just as the error says, the PinSettings component is not available for K20, since that is a legacy Kinetis part and PinSettings component was recently introduced. Moreover, KSDK does not support MK20DN512VLL10 (check release notes). The latest version 1.1.0 supports K60_100 MHz parts which are very similar, so you may try to customize the library for your K20 part, although this may not be an easy task and you cannot use Processor Expert. A migration guide is being developed but I do not have an estimated release time yet.
A different solution for you would be to start with the baremetal examples (KINETIS512_V2_SC), downloadable from the next link, under "Snippets, boot code...".
K20_100 |Kinetis 20 100 MHz MCUs|Freescale
Regards!,
Jorge Gonzalez
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