Hi Harshal,
Quick question: why do you need the MCXW72 for this setup? The RW612 is already a wireless MCU. You could just run your application directly on the RW612 and drop the extra microcontroller entirely.
If you go with the RW612, you can use the Mongoose networking library to handle your Wi-Fi and networking stacks. From there, you can focus directly on your application. There is a ready to use RW612 example here that can give you a good starting point.
To download it to your local workspace, open the link, select the 'Settings' panel and choose a destination directory. Then download the project to your computer by clicking the blue 'Generate C/C++' button. You can then open it with MCUXpresso IDE, build it, and flash it.
Heads up: I am part of the Mongoose development team, I hope this helps you in your project