Hi Senthil,
The LPC will respond correctly to the host if the host is sending the appropriate commands to the LPC54114.
Please check image below for the process.

Also, please make sure that you are configuring the SPI correctly on the host side:
SPI Config:
-Clock should not exceed 2 MHz.
-SPI SSEL to first clock timing should not be less than 100 us.
-SPI transfer configuration should be SPI Mode 0 with 8 data bits.
In addition I recommend you to read chapter 4.7 of the User Manual.
I hope this helps.
Best regards,
Felipe
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