> By internal you mean on the OEM board or the LPC4088 SOC itself?
I mean the silicon. Albeit it is only an assumption, MCU analogue input cicuitry is usually relatively sensitive to overvoltages or negative voltages.
You can check the schematics of your eval board, but I suspect there is not much protective circuitry. This is the way many eval boards are made.
Doing a short search, I suppose you speak about the board originally made by EA (Embedded Artists) which consists of a plugin OEM board, and a baseboard. EA does usually not publish schematics (only registered customers with login), but the board like quite "stuffed". Which leads me to the next point ...
> The LPC4088 has 8 AIN but the development board only reference 3 of them are the other just not > available with the OEM board? if not, why? It would be great if i can just assign the other AIN to these GPIO.
You would need to cross-check that with the datasheet (GPIOs with AIN functionality) and the schematics of your board.
But as stuffed as said (base-) board looks, the other GPIOs with possible AIN functionality are probably tied to other hardware like LCD, ext. memory or serial communication. That would almost certainly interfere with the analog functionality. Not sure if modifying the baseboard hardware would be an option.
This is why I usually prefer more "basic" boards, with most GPIOs routed to connectors. For which I make "custom specific" baseboards using veroboard when needed.
An alternative option would be an external ADC, possibly with SPI interface.