Hello Arvind_Srinivasan
Good Day!
I think there was a confusion, the x4 / x8 / x16 gains that the datasheets promise come from the PGA gain setting (an analog block), not from the digital calibration multiplier. If you only touch the “0.2 / 0.4 / 0.8” options, you are staying in the attenuation modes of the PGA and will never see >1× before calibration. The fix is to put the PGA into its gain modes 1,2,4,8,16
I recommend that you reread chapter 7.3.3 Programmable gain amplifier
I hope this information has helped you, please let me know if you need help with anything else.
Have a great day and best of luck.