Here's a table of 29 different "302" versions out of a total of 82 from 2012:
https://web.archive.org/web/20121002224302/http://www.freescale.com/webapp/sps/site/prod_summary.jsp...
That doesn't even list the "EN" and other variants. Nothing I can get to from there decodes the letters.
But from there I found a reference to "PCN5792" (7 Aug 2000) here:
https://www.nxp.com/docs/en/product-change-notice/PCN5792.pdf
MC68LC302PU20VCT 68LC302 TQFP 3.3V 20MHz
MC68LC302PU20CT 68LC302 TQFP 5.0V 20MHZ
So that says "VCT" is 3.3V and "CT" is 5.0V. Also that "The 'CT' part numbers
reflect that die can be sourced from either TSC8 or MOS11".
This current manual has a section at the end detailing "B" suffix is 5V and "VB" suffix is 3.3V:
https://www.nxp.com/docs/en/reference-manual/MC68LC302RM_AD.pdf
That also lists the high and low "VDD" limits for the 3.3V and 5V Parts.
So that's what the difference is.
This is detailed in the MC68LC302 Reference Manual (above) and in the Data Sheet:
https://www.nxp.com/docs/en/data-sheet/MC68LC302.pdf
Tom