If I can assume you are using CodeWarrior, then the linker FILL parameter:
ROM = READ_ONLY 0xF000 TO 0xFFAB FILL 0x83;
does a fine job of filling out the s19 file. As an adjunct, adding the paramater section:
CHECKSUM
CHECKSUM_ENTRY METHOD_CRC_CCITT
OF READ_ONLY 0xF000 TO 0xFFAB
INTO READ_ONLY 0xFFAC SIZE 2
UNDEFINED 0x83
END
END
will insert a CCITT checksum.