MCF52259 Coldfire Microcontroller DataSheet
2.1 Maximum Ratings
Table 4. Absolute Maximum Ratings
Digital Input Voltage -0.3 to 4.0 BUT
(4) All functional non-supply pins are internally clamped to Vss and Vdd.
From that I'd say that with the CPU power off the pin impedance is going to be one diode drop to ground.
So you either need a FET disconnecting the battery from the ADC input that is only turned on (from a GPIO) when you want to read the battery *OR* a very large resistor (100k or so) from the battery to the ADC pin. Select the resistor to be as high as possible, where the limiting factor is the error caused by the pin injection current.
Make sure you have a capacitor on that pin to filter it, and then work out the RC time it needs to be enabled to charge up, and the time it will hold when you start sampling and the ADC starts pulling current from it.
So read Section "2.15 Analog to Digital Converter", read Figure 14, then note where it also says:
"One aspect of this circuit is that there is an on-going input current, which is a function of the analog input voltage, VREF and the ADC clock frequency."
It says the equivalent input impedance is (1 / ((ADC Clock Rate) * (1.4*10^-12)))