Dear Albertini,
I viewed the screenshot, it shows the functions or methods in Bean PC_Master. To view "Properties" which are described in PE beans help pages, please click on the "Processor Expert" tab in Project View, then put your mouse on the Bean PC_Master and double-click your mouse, a window for Bean Inspector will pop up. The "Properties" are listed there.
Double click the Bean AsynchroSerial, Bean Inspector for this bean will pop up too. You can configure your SCI properties here, like SCI channel, baud rate…. PE will generate code to initializing SCI which is used for the communication between the target board and FreeMaster on your desktop.
Bean FreeMaster contains four functions/methods, you have marked them in your attached screenshot. You just need to drag them into your application code when perform sampling with FreeMaster. To view the description about these functions, please put your mouse on the function's name in project view, and right-click your mouse to select 'Help' iteam.
You may start from our example stationery project. Please create a new project from "Processor Expert Example Stationery", then select "TestAppplications-> Tools->pc_master ->…". Then:
1) Select a target like 'sdm pROM-xRAM', build the project and Click on 'Debug' icon to start debugging. The debugger stops at the beginning.
2) Open FreeMaster, click on 'File' Menu -> Open Project, then select 'sdm_pROM_xRAM.pmp', which is under the 'PC_Master' folder.
3) In FreeMaster GUI, click on 'Project' Menu -> 'Options', then go to 'MAP Files' tab.
Select the output elf file, please see my attached screenshot.
4) In CodeWarrior IDE, click on 'Debug' icon to run the project
5) In FreeMaster GUI, Click on 'File' Menu -> 'Start Communication', if it has already started, please ignore this step. The FreeMaster begins to work. You may click your mouse on either 'demo scope', or 'demo recorder' as you need.
More information about the operation on FreeMaster side, please refer to FMSTERUG (FreeMaster for Embedded Applications User Manual). You have already found it 
Best Regard
Fiona