Hello Peter,
For this application, I assume you would be using the KA8 device, with the availability of an ADC module. It would appear that the voltage regulator that you refer to is used internally, but does not affect the operation of this module. The reference voltage for the ADC would use internal connections to Vdd and Vss.
However, if the thermistor and resistor were to be series connected between Vdd and Vss, with the junction applied to an ADC input, the measurement would be ratiometric, and independent of actual Vdd level. With the thermistor in the upper leg, the ADC output value would be represented by the formula -
N = Nmax / (1 + Rth / R)
This would give an increasing value for increase of temperature (assuming NTC thermistor), but would be quite non-linear.
Regards,
Mac