Hi Ben
For different supply voltages you will get different ADC readouts - see the figure 1 of the AN3031, you need to know the supply voltage as Vtemp25 is stated for 3V supply in the datasheet.
So you need to know the correct supply voltage - the band gap voltage reference will help you to figure out (measure) what is the correct supply voltage (you will get ADC representation of 1.17V) and this way, you can recalculate ADC readout correctly to junction temperature of the chip.
there is also code for the AN attached in Freescale pages, so you can adapt it more easily to your MCU/ board.
Pavel