Hello,
With a minimum supply voltage level of 1.86 volts, you likely do not meet the condition for POR to occur. But this may be less than the minimum allowable operating supply voltage level, depending on the bus frequency used. The supply voltage below which POR is next triggered is subject to a unit-to-unit tolerance, but may be as low as 0.9 volts.
This is why the LVD reset condition is so important, especially since your voltage ramp is presumably very slow due to the presence of the supercap. Even when a POR occurs, at the point where the POR is released, the supply voltage may not be high enough to support your operating bus frequency. Enabling LVD reset will extend the reset duration until the supply voltage has risen sufficiently.
Regards,
Mac