Hi SyaZ,
Are you saying that you want some other voltage other than something approaching VDD?
If it is then the answer is no.
The voltage on an output pin set to high will be very close to VDD for a light load and will droop down to a slightly lower voltage as it is loaded higher. See specs for full details.
You may be able to use some form of PWM to simulate another voltage depending on the load.
Other than that you will need additional circuitry.
Slew rate control refers to the speed at which the voltage level changes - not its final level.